Rohit has three solutions X, Y and Z that have pH 2, 7 and 13 respectively. Which solution out of X, Y or Z will:
(a) liberate sulphur dioxide gas when heated with sodium sulphite?
(b) liberate ammonia gas when reacted with ammonium chloride?
(c) not have any effect on litmus paper?
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(a) X
Reason — Sodium sulphite reacts with an acid to liberate sulphur dioxide gas. Hence, solution X with pH 2 is acidic and will liberate sulphur dioxide.
SO32- + 2H+ ⟶ SO2 + H2O
(b) Z
Reason — Ammonium salts liberate ammonia gas on reaction with an alkali. Hence, solution Z with pH 13 is alkaline and will liberate ammonia from ammonium chloride.
NH4+ + OH- ⟶ NH3 + H2O
(c) Y
Reason — The solution Y with pH 7 will not have any effect on litmus paper as it is neither acidic nor basic.