Answer the following questions with respect to the electrolytic process in the extraction of aluminum:
(i) Identify the components of the electrolyte other than pure alumina and the role played by each.
(ii) Explain why powdered coke is sprinkled over the electrolytic mixture.
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(i) Cryolite and fluorspar are components of the electrolyte. Addition of cryolite enhances the conductivity of the mixture since, pure alumina is almost a non-conductor of electricity. Addition of both cryolite & fluorspar lowers the fusion point of the mixture i.e., mixture fuses around 950°C instead of 2050°C.
(ii) The layer of powdered coke is sprinkled over the electrolytic mixture as :
- it prevents burning of carbon electrodes in air at the emergence point from the bath.
- it minimizes or prevents heat loss by radiation.