Answer the following questions with respect to the electrolytic process in the extraction of aluminum:

ICSE Class 10 Chemistry PYQ · 2017 Paper · Section II

7(b)Written · 2017 · Section II · 2017 Paper

Answer the following questions with respect to the electrolytic process in the extraction of aluminum:

(i) Identify the components of the electrolyte other than pure alumina and the role played by each.

(ii) Explain why powdered coke is sprinkled over the electrolytic mixture.

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(i) Cryolite and fluorspar are components of the electrolyte. Addition of cryolite enhances the conductivity of the mixture since, pure alumina is almost a non-conductor of electricity. Addition of both cryolite & fluorspar lowers the fusion point of the mixture i.e., mixture fuses around 950°C instead of 2050°C.

(ii) The layer of powdered coke is sprinkled over the electrolytic mixture as :

  1. it prevents burning of carbon electrodes in air at the emergence point from the bath.
  2. it minimizes or prevents heat loss by radiation.
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